DEUTERIUM ENRICHMENT VIA SELECTIVE DISSOCIATION OF FLUOROFORM-D WITH A PULSED CO2-LASER

被引：52

作者：

TUCCIO, SA

HARTFORD, A

机构：

[1] Corporate Research Center, Allied Chemical Corporation, Morristown

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 65卷 / 02期

关键词：

D O I：

10.1016/0009-2614(79)87056-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Fluoroform-d undergoes multiphoton dissociation when irradiated with a pulsed CO2 laser and yields DF by unimoleclar elimination. Product analysis by infrared spectroscopy and gas chromatography shows that this process can be used to effect deuterium enrichment. A deuterium enrichment factor of greater than 5000 is obtained in natural fluoroform. © 1979.

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页码：234 / 239

页数：6

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