The laser-Raman spectra of hexaaminecobalt(III), chloropentaaminecobalt(III), and trans-dichlorotetraaminecobalt(III)

被引：19

作者：

Loehr, T. M. ^{[1
]}

Zinich, J. ^{[1
]}

Long, T. V., II ^{[2
]}

机构：

[1] Oregon Grad Ctr, Portland, OR 97225 USA

[2] Penn State Univ, Dept Chem, Whitmore Lab 212, University Pk, PA 16802 USA

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 7卷 / 02期

关键词：

D O I：

10.1016/0009-2614(70)80281-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The laser-Raman spectra of Co(NH3)(6)(3+) in cubic and distorted-octahedral environments, Co(NH3)(5)Cl2+ and trans-Co(NH3)(4)Cl-2(+) are reported and are empirically assigned. These spectra provide a basis for a discussion of ligand-ligand vibrational interactions in octahedral metal complexes.

引用

页码：183 / 186

页数：4

共 12 条

[1] BARROW GM, 1962, INORG NUCL CHEM, V2, P340
[2] BRAUER HG, 1954, HDB PREPARATIVEN ANO, P1148
[3] ON CO-N STRETCHING FREQUENCIES IN [CO(NH3)6]3+
HAAS, TE
HALL, JR
[J]. SPECTROCHIMICA ACTA, 1966, 22 (05): : 988 - &
[4] The Syntheses, Structures, and Laser Raman and Infrared Spectra of Co(NH3)(6)CuCl5, [Co(NH3)(5)OH2] CuCl5, Co(NH3)(6)CdCl5, Co(NIH3)(6)ZnCl5, and Co(NH3)(6)ZnCl4(NO3)
Long, Thomas Veach, II
Herlinger, Albert W.
Epstein, Earl F.
Bernal, Ivan
[J]. INORGANIC CHEMISTRY, 1970, 9 (03) : 459 - 464
[5] The Crystal Structure of Hexaamminecobalt(III) Tetrachlorozincate(II) Chloride, [Co(NH3)(6)] [ZnCl4]Cl
Meek, Devon W.
Ibers, James A.
[J]. INORGANIC CHEMISTRY, 1970, 9 (03) : 465 - 470
[6] FAR INFRA-RED SPECTRA AND METAL-LIGAND FORCE CONSTANTS OF METAL AMMINE COMPLEXES
NAKAGAWA, I
SHIMANOUCHI, T
[J]. SPECTROCHIMICA ACTA, 1966, 22 (04): : 759 - +
[7] THE INFRARED SPECTRA OF SOME METAL AMMINES AND DEUTEROAMMINES
POWELL, DB
SHEPPARD, N
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1956, (AUG): : 3108 - 3113
[8] INFRARED SPECTRA FROM 80 TO 2000 CM.-1 OF SOME METAL-AMMINE COMPLEXES
SACCONI, L
GANS, P
SABATINI, A
[J]. INORGANIC CHEMISTRY, 1964, 3 (12) : 1772 - &
[9] SCHLESSINGER G, 1960, INORG SYNTHESIS, V6, P182
[10] INFRARED SPECTROSCOPIC STUDY ON THE CO-ORDINATION BOND .1. INFRARED SPECTRA OF COBALT HEXAMMINE, PENTAMMINE AND TRANS-TETRAAMMINE COMPLEXES
SHIMANOUCHI, T
NAKAGAWA, I
[J]. SPECTROCHIMICA ACTA, 1962, 18 (01): : 89 - 100

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