A NEW REAGENT FOR A VERY SIMPLE AND EFFICIENT DETERMINATION OF ENANTIOMERIC PURITY OF ALCOHOLS BY P-31 NMR

被引：62

作者：

ALEXAKIS, A

MUTTI, S

NORMANT, JF

MANGENEY, P

机构：

[1] Laboratoire de Chimie des Organo-Eléments, CNRS UA 473 Université P. et M. Curie, F-75252 Paris Cedex 05, 4, Place Jussie

来源：

TETRAHEDRON-ASYMMETRY | 1990年 / 1卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(00)86347-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new reagent is described for the determination of enantiomeric excess of chiral alcohols. This derivatizing agent allows an accurate analysis by 31P NMR. A large array of primary, secondary, and tertiary alcohols, functionalized or not, were successfully tested. Reagent 7 is easy to prepare and reacts alone with the chiral alcohol, at room temperature, eventually directly in the NMR tube. © 1990.

引用

页码：437 / 440

页数：4

共 8 条

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