REACTION OF O-ALLYL GLUCOSE WITH [(PH3P)2RHCL]2 - AN INTRAMOLECULAR H-2 TRANSFER

被引：5

作者：

GABLE, KP

机构：

[1] Department of Chemistry, Oregon State University, Corvallis

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 01期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)71208-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of 3-O-allyl glucose with [Ph3P)2RhCl]2 at temperatures below 60-degrees-C leads to isomerization of the double bond to form a vinyl ether. Reaction at temperatures above 100-degrees-C in N-methylpyrrolidone leads to formation of propyl and propenyl glucono-[1,4]-lactone derivatives, identified as their triacetates, as well as to a decarbonylated product.

引用

页码：23 / 26

页数：4

共 16 条

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