UNCHARGED ATOMIC OXYGEN IN OXIDATIVE CONVERSION OF C1-C2 ALKANES

被引:5
作者
ANSHITS, AG [1 ]
机构
[1] USSR ACAD SCI,INST CHEM NAT ORGAN MAT,KRASNOYARSK 660049,USSR
关键词
D O I
10.1016/0920-5861(92)80070-4
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The role of uncharged atomic oxygen species in oxidative conversion of CH4 and C2H6 has been considered. It is shown that active atomic oxygen species participate in C1-C2 alkanes conversion in the presence of N2O on zeolites, in the CH4-N2O and CH4-O2 systems on transition metal silicides and nitrides, as well as hydrocarbon oxidation during N2O and O3 photolysis by excimer laser light. Participation of uncharged oxygen species in conversion of light alkanes makes it possible to explain not only hydrocarbon formation pathways, but those of oxygen-containing compounds as well.
引用
收藏
页码:495 / 501
页数:7
相关论文
共 16 条
[1]  
AIKA K, 1983, 7TH SOV JAP CAT SEM, P58
[2]   GAS-PHASE RADICAL FORMATION DURING THE REACTIONS OF METHANE, ETHANE, ETHYLENE, AND PROPYLENE OVER SELECTED OXIDE CATALYSTS [J].
DRISCOLL, DJ ;
LUNSFORD, JH .
JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (21) :4415-4418
[3]   FORMATION OF GAS-PHASE METHYL RADICALS OVER MGO [J].
DRISCOLL, DJ ;
MARTIR, W ;
WANG, JX ;
LUNSFORD, JH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (01) :58-63
[4]   OXIDATIVE COUPLING OF METHANE USING OXIDE CATALYSTS [J].
HUTCHINGS, GJ ;
SCURRELL, MS ;
WOODHOUSE, JR .
CHEMICAL SOCIETY REVIEWS, 1989, 18 (03) :251-283
[5]  
ILCHENKO NI, 1991, TEORET EXPER HIMIYA, P231
[6]  
ILCHENKO NI, 1991, KINET KATAL, V32, P873
[7]  
KHALIF VA, 1978, KINET KATAL, V19, P1234
[8]  
OSHIMA Y, 1989, SEKIYU GAKKAISHI, V32, P216
[9]  
OSHIMA Y, 1989, SEKIYU GAKKAISHI, V32, P59
[10]  
PANOV GI, 1990, 1ST TOK C ADV CAT SC