THE SYNTHESIS OF OCTAHEDRAL MIXED BIS-ALKYNE AND ALKYNE ALKENE COMPLEXES OF TUNGSTEN

被引：12

作者：

CLARK, GR

NIELSON, AJ

RAE, AD

RICKARD, CEF

机构：

[1] UNIV AUCKLAND,DEPT CHEM,AUCKLAND,NEW ZEALAND

[2] UNIV NEW S WALES,DEPT CHEM,SYDNEY,NSW,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 15期

关键词：

D O I：

10.1039/c39920001069

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Replacement of a phosphine ligand in [WCl2(PhC2Ph)(PMe3)3] by PhC = CPh, PhC = CH and HC = CH, or reduction of [WCl3(PhC2Ph)(PMe3)2] in the presence of MeC2Me and Me(CH2)2C2Me yields mixed bis-alkyne complexes; under ethylene or propene the reduction reactions afford mixed alkyne-alkene complexes, and the structure of [WCl2(PhC2Ph)(CH2 = CH2)(PMe3)2] has been confirmed by X-ray crystallography.

引用

页码：1069 / 1070

页数：2

共 9 条

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