RING-OPENING POLYMERIZATION OF METALLOCENOPHANES

被引：85

作者：

MANNERS, I

机构：

[1] Department of Chemistry, University of Toronto, Toronto, Ontario, M5S 1A1

来源：

ADVANCED MATERIALS | 1994年 / 6卷 / 01期

关键词：

D O I：

10.1002/adma.19940060115

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The development of processable high molecular weight polymers with skeletal transition metal atoms represents a synthetic challenge that, if overcome, can be expected to yield a variety of materials with novel electrical, optical, magnetic, or preceramic properties. Recent work has shown that the ring-opening polymerization (ROP) of strained, ring-tilted [1]- or [2]metallocenophanes provides a route to a variety of well-defined, ferrocene-backbone polymers with molecular weights of over 1000000 in several cases.

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页码：68 / 71

页数：4

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