ELECTRONIC-STRUCTURE OF LIGHT TRANSITION-METAL COMPOUNDS STUDIED BY PHOTOEMISSION

被引：23

作者：

SHIN, S ^{[1
]}

TEZUKA, Y ^{[1
]}

ISHII, T ^{[1
]}

UEDA, Y ^{[1
]}

机构：

[1] UNIV TOKYO, INST SOLID STATE PHYS, MINATO KU, TOKYO 106, JAPAN

来源：

SOLID STATE COMMUNICATIONS | 1993年 / 87卷 / 11期

关键词：

D O I：

10.1016/0038-1098(93)90559-6

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

The valence band photoemission has been measured on ScF3, TiO2, and V2O5 which have no 3d electron nominally. The charge-transfer satellites are found in the region from 11 eV to 17 eV below the top of the valence band. It is concluded from the resonant photoemission that the charge-transfer-type configuration is manifest to form the valence state in the ground state in addition to the originally filled-up 2p state of ligand.

引用

页码：1051 / 1054

页数：4

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