MASS SPECTROMETRIC STUDY OF REACTIONS OF ATOMIC OXYGEN WITH ETHYLENE AND FORMALDEHYDE

被引：58

作者：

HERRON, JT

PENZHORN, RD

机构：

[1] National Bureau of Standards, Washington

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 01期

关键词：

D O I：

10.1021/j100721a031

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A mass spectrometric study has been made of the reactions of atomic oxygen with ethylene and formaldehyde. The formation of formaldehyde in the ethylene reaction is shown to be independent of the presence of molecular oxygen and is attributed to a reaction between atomic oxygen and methyl radicals. The rate constant for the reaction of atomic oxygen with formaldehyde is 9.0 × 1010 cm3 mol-1 sec-1 at 300°K.

引用

页码：191 / &

共 26 条

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