POLAROGRAPHY IN ETHYLENE SULFITE

被引:15
作者
GUTMANN, V
DUSCHEK, O
机构
[1] Institut für Anorganische Chemie der Technischen Hochschule Wien, Wien
来源
MONATSHEFTE FUR CHEMIE | 1969年 / 100卷 / 03期
关键词
D O I
10.1007/BF00900592
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The polarographic and oscillopolarographic behaviour of Tl(I), Cu(II), Zn(II), Cd(II), Mn(II), Co(II), Ni(II) as well as of Bisbiphenylchromium(I)iodide is described in 0,1 m-[(C2H5)4N]ClO4-solutions in anhydrous ethylene sulphite. The nature of the limiting currents, the diffusion coefficients, the diffusion current constants, the half wave potentials vs. an aqueous saturated calomel electrode and the temperature dependence, the reversibility or irreversibility of the electrochemical processes and the influence of small amounts of water have been determined. © 1969 Springer-Verlag.
引用
收藏
页码:1047 / &
相关论文
共 21 条