N-FLUORO-BIS(TRIFLUOROMETHANESULFONYL)IMIDE - AN IMPROVED SYNTHESIS

被引：65

作者：

DESMARTEAU, DD

WITZ, M

机构：

[1] Howard L. Hunter Chemistry Laboratory, Clemson University, Clemson

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1991年 / 52卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)80317-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An improved synthesis of (CF3SO2)2NH and its conversion to the very useful fluorination reagent (CF3SO2)2NF is described. The five-step synthesis yields (CF3SO2)2NF in 76% yield based on the starting CF3SO2F.

引用

页码：7 / 12

页数：6

共 10 条

[1] N-FLUORO-N-ALKYLSULFONAMIDES - USEFUL REAGENTS FOR THE FLUORINATION OF CARBANIONS [J].

BARNETTE, WE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (02) :452-454

[2]

DESMARTEAU DD, UNPUB

[3] SYNTHESIS, PROPERTIES, AND REACTIONS OF BIS((TRIFLUOROMETHYL)SULFONYL) IMIDE, (CF3SO2)2NH [J].

FOROPOULOS, J ;

DESMARTEAU, DD .

INORGANIC CHEMISTRY, 1984, 23 (23) :3720-3723

[4] STEREOSPECIFIC SYNTHESIS OF ALKENYL FLUORIDES (WITH RETENTION) VIA ORGANOMETALLIC INTERMEDIATES [J].

LEE, SH ;

SCHWARTZ, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (09) :2445-2447

[5] SELECTIVE FLUORINATIONS WITH 1-FLUORO-2-PYRIDONE [J].

PURRINGTON, ST ;

JONES, WA .

JOURNAL OF FLUORINE CHEMISTRY, 1984, 26 (01) :43-46

[6] 1-FLUORO-2-PYRIDONE - A USEFUL FLUORINATING REAGENT [J].

PURRINGTON, ST ;

JONES, WA .

JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (05) :761-762

[7] N-FLUOROPERFLUOROALKYLSULFONIMIDES - REMARKABLE NEW FLUORINATION REAGENTS [J].

SINGH, S ;

DESMARTEAU, DD ;

ZUBERI, SS ;

WITZ, M ;

HUANG, HN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (23) :7194-7196

[8] N-FLUOROPYRIDINIUM TRIFLATE AND ITS ANALOGS, THE 1ST STABLE 1-1 SALTS OF PYRIDINE NUCLEUS AND HALOGEN ATOM [J].

UMEMOTO, T ;

TOMITA, K .

TETRAHEDRON LETTERS, 1986, 27 (28) :3271-3274

[9] N-FLUOROPYRIDINIUM TRIFLATE AND ITS DERIVATIVES - USEFUL FLUORINATING AGENTS [J].

UMEMOTO, T ;

KAWADA, K ;

TOMITA, K .

TETRAHEDRON LETTERS, 1986, 27 (37) :4465-4468

[10]

1988, 12TH INT S FLUOR CHE

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