Triple complex formation in the excited state

被引：138

作者：

Beens, H. ^{[1
]}

Weller, A.

机构：

[1] Vrije Univ Amsterdam, Chem Lab, Amsterdam, Netherlands

[2] Max Planck Inst Spektroskopie, Gottingen, Germany

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 2卷 / 03期

关键词：

D O I：

10.1016/0009-2614(68)85025-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two fluorescence transformations observed with the system. naphthalene (D) - 1.4-dicyanobenzene (A). when first the azceptor and then the donor concentration is increased are shown to be due to charge-transfer complex (D(+)A(-)) and subsequent triple complex (DD(.)A(-)) formation in the excited state. Both excited complexes have high dipole moments. The oxidation potential of the naphthalene dimer (in the ground state) is estimated as E(DD/DD+) = 1.1 volt versus SCE.

引用

页码：140 / 142

页数：3

共 15 条

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