REDUCTIVE CLEAVAGE OF C-OH BONDS IN ALLYL POSITION - FORMATION OF GASEOUS PRODUCTS IN THE COURSE OF THE CATHODIC REDUCTION OF SOME SIMPLE UNSATURATED ALCOHOLS

被引：39

作者：

HORANYI, G

INZELT, G

TORKOS, K

机构：

[1] EOTVOS LORAND UNIV, DEPT PHYS CHEM & RADIOL, H-1088 BUDAPEST, HUNGARY

[2] EOTVOS LORAND UNIV, DEPT GEN & INORGAN CHEM, H-1088 BUDAPEST, HUNGARY

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1979年 / 101卷 / 01期

关键词：

D O I：

10.1016/S0022-0728(79)80082-0

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The problem of the reductive cleavage of C-OH bonds in allyl position has been considered starting from the literature data concerning the behaviour of allyl alcohol. The formation of hydrocarbons has been shown in the case of the electroreduction of crotyl alcohol, 2-butene-1,4-diol, propargyl alcohol, 2-butyne-1,4-diol and 1-butyne-3-ol. The composition of the gaseous products was analyzed, current efficiency values with respect to the hydrocarbon formation were calculated. Schemes for the reduction path were given. © 1979 Elsevier Sequoia S.A., Lausanne.

引用

页码：101 / 108

页数：8

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