EXCESS HEAT-CAPACITIES OF BINARY-MIXTURES OF CARBON-TETRACHLORIDE WITH N-ALKANES AT 298.15-K

被引：23

作者：

GROLIER, JPE ^{[1
]}

HAMEDI, MH ^{[1
]}

WILHELM, E ^{[1
]}

KEHIAIAN, HV ^{[1
]}

机构：

[1] CNRS,CTR RECH MICROCALORIMETRIE & THERMOCHIM,F-13003 MARSEILLE,FRANCE

来源：

THERMOCHIMICA ACTA | 1979年 / 31卷 / 01期

关键词：

D O I：

10.1016/0040-6031(79)80010-6

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A Picker flow microcalorimeter was used to determine molar excess heat capacities CPE at 298.15 K for mixtures of carbon tetrachloride + n-heptane, n-nonane, and n-decane. The excess heat capacities are negative in all cases. The absolute value |CPE| increases with increasing chain length of the alkane. A formal interchange parameter, cP12, is calculated and its dependence on n-alkane chain length is discussed briefly in terms of molecular orientations. © 1979.

引用

页码：79 / 84

页数：6

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