SYNTHESIS, STRUCTURE AND PROPERTIES OF STEREOCHEMICALLY NON-RIGID MOLYBDENUM PYRAZOLYLBORATO COMPLEXES CONTAINING A DIHAPTO-THIOCARBOXAMIDO LIGAND

被引：12

作者：

DESMOND, T

LALOR, FJ

OSULLIVAN, B

FERGUSON, G

机构：

[1] NATL UNIV IRELAND UNIV COLL CORK,DEPT CHEM,CORK,IRELAND

[2] UNIV GUELPH,DEPT CHEM & BIOCHEM,GUELPH N1G 2W1,ONTARIO,CANADA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 381卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0022-328X(90)80122-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pyrazolylboratomolybdenum complexes containing the η2-CSNMe2 ligand have been prepared by treating the appropriate carbonylmetallate anion with Me2NCSCl. The structure of pzB(pz)3Mo(CO)2(η2-CSNMe2 ) (IIIb) has been established by X-ray crystallographic methods. The 1H and 13C NMR spectra of IIIb show evidence for two separate intramolecular dynamic processes in solution. Complex IIIb can be alkylated at the sulphur atom and forms 1/1 complexes with mercuric halides. © 1990.

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页码：C33 / C37

页数：5

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