A MODIFIED SYNTHESIS OF RUTHENIUM(II) HEXAAQUA SALTS

被引：50

作者：

BERNHARD, P ^{[1
]}

BINER, M ^{[1
]}

LUDI, A ^{[1
]}

机构：

[1] UNIV BERN,INST ANORGAN CHEM,CH-3000 BERN 9,SWITZERLAND

来源：

POLYHEDRON | 1990年 / 9卷 / 08期

关键词：

D O I：

10.1016/S0277-5387(00)81300-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An efficient preparation of ruthenium aqua ions starts from the hydrated dioxide. Oxidation by periodate produces ruthenium tetroxide which is reduced by metallic lead to [Ru(H2O)6]2+. Ion exchange and crystallization affords pure [Ru(H2O)6](tos)2 (tos = p-toluenesulphonate) in 70-80% yield. © 1990.

引用

页码：1095 / 1097

页数：3

共 10 条

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