PROPYNE OXIDATION - A KINETIC MODELING STUDY

被引：30

作者：

DAGAUT, P

CATHONNET, M

BOETTNER, JC

机构：

[1] C.N.R.S. Centre de Recherches sur la Chimie de la, Combustion et des Hantes Temperatures, 45071 Orleans Cedex 2, 1C, Avenue de la Recherches Scientifique

来源：

COMBUSTION SCIENCE AND TECHNOLOGY | 1990年 / 71卷 / 1-3期

关键词：

combustion; hydrocarbon; ignition delay; kinetics; modeling; propyne;

D O I：

10.1080/00102209008951627

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Propyne oxidation was modeled using a comprehensive kinetic reaction mechanism including the most recent findings concerning the kinetics of the reactions involved in the oxidation of propyne. The proposed mechanism is able to reproduce experimental data obtained in our high-pressure jet stirred reactor and in shock tube in the pressure range 1 - 13 atm, for temperatures extending from 950 to 2000 K and equivalence ratios 0.5 to 2. The proposed propyne oxidation mechanism is able to correctly reproduce ignition delay times measured in shock tube and molecular species concentrations measured in our jet stirred reactor. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：111 / 128

页数：18

共 30 条

[1]

ABOUSSI B, 1987, ETUDE OXYDATION PROP

[2] GAS-PHASE PYROLYSIS OF CYCLOPROPENE .1. KINETICS AND MECHANISM [J].

BAILEY, IM ;

WALSH, R .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1978, 74 :1146-1158

[3]

BOETTNER JC, 1988, NATO ASI SERIES E, V140, P421

[4]

Burcat A, 1984, COMBUSTION CHEM

[5] KINETIC-STUDY OF N-BUTANE OXIDATION [J].

CHAKIR, A ;

CATHONNET, M ;

BOETTNER, JC ;

GAILLARD, F .

COMBUSTION SCIENCE AND TECHNOLOGY, 1989, 65 (4-6) :207-230

[6] KINETIC MODELING OF ETHYLENE OXIDATION [J].

DAGAUT, P ;

CATHONNET, M ;

BOETTNER, JC ;

GAILLARD, F .

COMBUSTION AND FLAME, 1988, 71 (03) :295-312

[7] KINETIC MODELING OF PROPANE OXIDATION [J].

DAGAUT, P ;

CATHONNET, M ;

BOETTNER, JC ;

GAILLARD, F .

COMBUSTION SCIENCE AND TECHNOLOGY, 1987, 56 (1-3) :23-63

[8] A JET-STIRRED REACTOR FOR KINETIC-STUDIES OF HOMOGENEOUS GAS-PHASE REACTIONS AT PRESSURES UP TO 10-ATMOSPHERES (APPROXIMATELY 1 MPA) [J].

DAGAUT, P ;

CATHONNET, M ;

ROUAN, JP ;

FOULATIER, R ;

QUILGARS, A ;

BOETTNER, JC ;

GAILLARD, F ;

JAMES, H .

JOURNAL OF PHYSICS E-SCIENTIFIC INSTRUMENTS, 1986, 19 (03) :207-209

[9] EXPERIMENTAL-STUDY AND KINETIC MODELING OF PROPENE OXIDATION IN A JET STIRRED FLOW REACTOR [J].

DAGAUT, P ;

CATHONNET, M ;

BOETTNER, JC .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (03) :661-671

[10]

DAGAUT P, 1989, UNPUB ALLENE OXIDATI

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