TRIS(ETHYLMALTOLATO)BISMUTH(III)

被引：10

作者：

BURGESS, J

FAWCETT, J

PARSONS, SA

RUSSELL, DR

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270194006463

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination around the Bi atom of the title compound, tris(2-ethyl-3-hydroxy-4H-pyran-4-onato-O-3,O-4)bismuth(III), [Bi(C7H7O3)(3)], can be described as a distorted pentagonal bipyramid with five of the six coordinated O atoms approximately in the equatorial plane and the axial positions occupied by the sixth coordinated O atom and a stereoactive lone pair. This is a rare example of a six-coordinate Bi-III compound with a stereoactive lone pair.

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页码：1911 / 1913

页数：3

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