ACTIVATION PARAMETERS FOR ELECTRON TRANSFER BETWEEN CYCLOOCTATETRAENE DIANION AND ANION RADICAL

被引：21

作者：

SMENTOWSKI, FJ

STEVENSO.GR

机构：

[1] Chemistry Department, Texas A&M University, College Station

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 26期

关键词：

D O I：

10.1021/ja01054a031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rate constants and activation parameters have been determined for electron transfer between cyclooctatetraene (COT) dianion and the anion radical for various COT-solvent-M (where M = Li, Na, K) systems. As determined by electron spin and nuclear magnetic resonance, the rate constant for electron transfer (eq 1) is very dependent upon the solvent and the counterion. Even in ammonia, a relatively protic and ionizing solvent, the rate of electron transfer is dependent upon the counterion. Possible line-broadening mechanisms in this solvent are discussed. © 1969, American Chemical Society. All rights reserved.

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页码：7401 / +

页数：1

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