EVALUATION OF KINETIC-PARAMETERS AND MECHANISMS OF COMPLEX-REACTIONS FROM THERMAL-ANALYSIS DATA

被引：4

作者：

GONTKOVSKAYA, WT

GORDOPOLOVA, IS

PEREGUDOV, AN

机构：

[1] Institute of Structural Macrokinetics, USSR Academy of Sciences, Chernogolovka, Moscow Region

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 1990年 / 36卷 / 02期

关键词：

D O I：

10.1007/BF01914527

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A method is for TA data-processing: the method of exponential multipliers (MEM). The application of this method permits determination of the steps of the process, the type of the kinetic function, the type of the reaction and the kinetic parameters of the reaction steps. The method is simple and is easily carried out with the use of a mini-computer. The efficiency of the method is illustrated on the example of the thermal decomposition of ammonia copper chromate. The mechanism of the process and the kinetic constants were determined. They agree with available literature data. © 1990 Wiley Heyden Ltd, Chichester and Akadémiai Kiadó, Budapest.

引用

页码：791 / 807

页数：17