POLYPYRIDINE COMPLEXES OF IRON USED AS REDOX SHUTTLES FOR OVERCHARGE PROTECTION OF SECONDARY LITHIUM BATTERIES

被引：34

作者：

CHA, CS

AI, XP

YANG, HX

机构：

[1] Chemistry Department, Wuhan University, Wuhan

来源：

JOURNAL OF POWER SOURCES | 1995年 / 54卷 / 02期

关键词：

SECONDARY LITHIUM BATTERIES; POLYPYRIDINE; IRON; REDOX SHUTTLES;

D O I：

10.1016/0378-7753(94)02079-I

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The 2,2'-bipyridyl and 1,10-phenanthroline complexes of iron, which show oxidation potential similar to 0.7 V more positive than that of ferrocene, were studied for their possible use as redox shuttles for the overcharge protection of secondary lithium batteries. The shuttle voltage was found to be around 3.8-3.9 V. The electrochemical stability of these complexes at the electrodes of lithium batteries was also investigated.

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收藏

页码：255 / 258

页数：4

相关论文

共 14 条

[1] NORMAL-BUTYLFERROCENE FOR OVERCHARGE PROTECTION OF SECONDARY LITHIUM BATTERIES [J].

ABRAHAM, KM ;

PASQUARIELLO, DM ;

WILLSTAEDT, EB .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (06) :1856-1857

[2] DIRECTIONS IN SECONDARY LITHIUM BATTERY RESEARCH-AND-DEVELOPMENT [J].

ABRAHAM, KM .

ELECTROCHIMICA ACTA, 1993, 38 (09) :1233-1248

[3] IDENTIFICATION OF SURFACE-FILMS FORMED ON LITHIUM IN DIMETHOXYETHANE AND TETRAHYDROFURAN SOLUTIONS [J].

AURBACH, D ;

DAROUX, ML ;

FAGUY, PW ;

YEAGER, E .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1988, 135 (08) :1863-1871

[4] THE BEHAVIOR OF LITHIUM ELECTRODES IN MIXTURES OF ALKYL CARBONATES AND ETHERS [J].

AURBACH, D ;

GOFER, Y .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (12) :3529-3536

[5] THE ELECTROCHEMICAL-BEHAVIOR OF LITHIUM SALT-SOLUTIONS OF GAMMA-BUTYROLACTONE WITH NOBLE-METAL ELECTRODES [J].

AURBACH, D .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (04) :906-913

[6] IDENTIFICATION OF SURFACE-FILMS FORMED ON LITHIUM IN PROPYLENE CARBONATE SOLUTIONS [J].

AURBACH, D ;

DAROUX, ML ;

FAGUY, PW ;

YEAGER, E .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (07) :1611-1620

[7]

CHA S, 1994, J ELECTROANAL CHEM, V368, P47

[8]

CHUSID O, 1993, J POWER SOURCES, V43, P47, DOI 10.1016/0378-7753(93)80101-T

[9]

GOLOVIN MN, 1992, J ELECTROCHEM SOC, V139, P5, DOI 10.1149/1.2069200

[10]

LI S, 1993, J POWER SOURCES, V43, P533