ABSOLUTE-CONFIGURATION OF DI(PERCHLORATO-O)TETRA(PYRIDINE-N)COPPER(II), [CU(CLO4)2(PY)4]

被引：12

作者：

AGNUS, Y ^{[1
]}

LABARELLE, M ^{[1
]}

LOUIS, R ^{[1
]}

METZ, B ^{[1
]}

机构：

[1] IBMC,CNRS,UPR BIOL STRUCT 9004,F-67084 STRASBOURG,FRANCE

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193009813

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal of the title complex consists of neutral [Cu(ClO4)2(C5H5N)4] units. The two perchlorate ligands occupy the axial positions of a distorted octahedral environment around the metal ion; the axial Cu-O bonds are relatively weak. The absolute configuration has been established; the four pyridine molecules display a right-handed screw arrangement around the Cu2+ ion.

引用

页码：536 / 538

页数：3

共 15 条

[1] COORDINATING PROPERTIES OF FLUOROSULFATE ION - TETRAKIS(PYRIDINE)COMPLEXES OF ZINC(II), COPPER(II), AND NICKEL(II) FLUOROSULFATES [J].

ALLEYNE, CS ;

THOMPSON, RC .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1974, 52 (18) :3218-3228

[2] THE ESR-SPECTRUM AND STRUCTURE OF TETRAPYRIDINE COPPER(II) PERCHLORATE [J].

BARKER, PJ ;

STOBART, SR .

INORGANICA CHIMICA ACTA-LETTERS, 1980, 45 (05) :L197-L198

[3] PYRIDINE GAMMA-PICOLINE AND QUINOLINE COMPLEXES OF TRANSITION METAL PERCHLORATES AND TETRAFLUOROBORATES [J].

BROWN, DH ;

NUTTALL, RH ;

MCAVOY, J ;

SHARP, DWA .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (07) :892-&

[4]

Cromer D.T, 1974, INT TABLES XRAY CRYS, VIV

[5] PERCHLORATE ION COMPLEXES [J].

GOWDA, NMN ;

NAIKAR, SB ;

REDDY, GKN .

ADVANCES IN INORGANIC CHEMISTRY, 1984, 28 :255-299

[6] SIGNIFICANCE TESTS ON CRYSTALLOGRAPHIC R FACTOR [J].

HAMILTON, WC .

ACTA CRYSTALLOGRAPHICA, 1965, 18 :502-&

[7]

Hamm D.J., 1973, INORG CHIM ACTA, V7, P637

[8] DISPERSION CORRECTIONS + CRYSTAL STRUCTURE REFINEMENTS [J].

IBERS, JA ;

HAMILTON, WC .

ACTA CRYSTALLOGRAPHICA, 1964, 17 (06) :781-&

[9] THE UNIT CELL AND SPACE GROUP OF TETRAPYRIDINECOPPER(II)FLUOBORATE [J].

IBERS, JA .

ACTA CRYSTALLOGRAPHICA, 1953, 6 (04) :367-367

[10]

JOHNSON CK, 1976, ORNL5138 REP

← 1 2 →