ANALYSIS OF ESTOLIDES IN TECHNICAL HYDROXYLATED FATTY-ACIDS FROM PLANT OILS

被引：3

作者：

FEHLING, E

机构：

[1] Institut für Biochemie und Technologie der Fette, H.P. Kaufmann-Institut, Bundesanstalt für Getreide-, Kartoffel- und Fettforschung, Detmold, D-32756

来源：

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY | 1995年 / 72卷 / 03期

关键词：

9,10-DIHYDROXY OCTADECANOIC ACID; DIHYDROXY TETRAHYDROFURAN OCTADECANOIC ACIDS; ESTOLIDES; GEL PERMEATION CHROMATOGRAPHY; HYDROXYLATED FATTY ACIDS;

D O I：

10.1007/BF02541096

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Cel permeation chromatography of hydroxylated fatty acids (HOFA), prepared from various plant oils by a novel technical process, showed the presence of considerable amounts of estolides formed by intermolecular esterification of the HOFA. Thin-layer chromatographic fractionation followed by gas chromatography of the fractions revealed that the nonpolar estolides contain predominantly saturated fatty acids esterified to three-9,10-dihydroxy octadecanoic acid or dihydroxy tetrahydrofuran octadecanoic acids, e.g., 9,12-dihydroxy-10,13-epoxy octadecanoic acid and 10,13-dihydroxy-9,12-epoxy octadecanoic acid. The fractions of polar estolides consist mainly of intermolecular esters of the above dihydroxy fatty acids.

引用

页码：355 / 359

页数：5

共 18 条

[1] PRODUCTS OF THE DIMERIZATION OF UNSATURATED FATTY-ACIDS .9. KINETIC-STUDIES ABOUT THE DIMERIZATION OF LINOLEIC-ACID [J].

ADELHARDT, R ;

SPITELLER, G .

FETT WISSENSCHAFT TECHNOLOGIE-FAT SCIENCE TECHNOLOGY, 1993, 95 (03) :85-90

[2]

Bagby M, 1989, FATS FUTURE, P301

[3] EPOXY LIPIDS FROM THE AUSTRALIAN EPIPHYTIC BROWN ALGA NOTHEIA-ANOMALA [J].

BARROW, RA ;

CAPON, RJ .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1990, 43 (05) :895-911

[4] PRODUCTS OF THE DIMERIZATION OF UNSATURATED FATTY-ACIDS .10. IDENTIFICATION OF ESTOLIDES IN EARLY PHASE OF THE DIMERIZATION [J].

BRUTTING, R ;

SPITELLER, G .

FETT WISSENSCHAFT TECHNOLOGIE-FAT SCIENCE TECHNOLOGY, 1993, 95 (05) :193-199

[5] FATTY ACIDS OF BROWN + YELLOW FAT IN RATS [J].

CHALVARDJIAN, A .

BIOCHEMICAL JOURNAL, 1964, 90 (03) :518-&

[6]

CHRISTIE WW, 1989, GAS CHROMATOGRAPHY L, P78

[7]

CHRISTOPHERSON WM, 1987, HEPATIC BILIARY CANC, P17

[8] POLYHYDROXY FATTY-ACIDS AND THEIR DERIVATIVES FROM PLANT OILS [J].

DAHLKE, B ;

HELLBARDT, S ;

PAETOW, M ;

ZECH, WH .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1995, 72 (03) :349-353

[9] HIGH-PERFORMANCE SIZE EXCLUSION CHROMATOGRAPHY OF POLAR COMPOUNDS IN HEATED AND NON-HEATED FATS [J].

DOBARGANES, MC ;

PEREZCAMINO, MC ;

MARQUEZRUIZ, G .

FETT WISSENSCHAFT TECHNOLOGIE-FAT SCIENCE TECHNOLOGY, 1988, 90 (08) :308-311

[10] ESTOLIDES FROM MEADOWFOAM OIL FATTY-ACIDS AND OTHER MONOUNSATURATED FATTY-ACIDS [J].

ERHAN, SM ;

KLEIMAN, R ;

ISBELL, TA .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1993, 70 (05) :461-465

← 1 2 →