INFLUENCE OF IONIC-STRENGTH ON THE EQUILIBRIUM-CONSTANT OF AN ION-MOLECULE REACTION

被引：56

作者：

SMETANA, AJ ^{[1
]}

POPOV, AI ^{[1
]}

机构：

[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 1979年 / 11卷 / 12期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0021-9614(79)90106-X

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Concentration formation constants for the 18-crown-6-sodium ion complex in anhydrous methanol solutions were measured as a function of the ionic strength of the solution. The Kc values remained reasonably constant for Ic ≤ 0.05 mol dm-3 At higher ionic strengths the Kc values begin to decrease. The infinite-dilution formation constant was 2.2 × 104. © 1979.

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页码：1145 / 1149

页数：5

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