THE CARBOXYLATION OF SATURATED-HYDROCARBONS BY GIF SYSTEMS (FE(0)/CO/O2 AND CU(0)/CO/O2 IN PYRIDINE-ACETIC ACID)

被引：17

作者：

BARTON, DHR

CSUHAI, E

DOLLER, D

机构：

[1] Department of Chemistry, Texas A and M University. College Station

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 31期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)60091-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Saturated hydrocarbons are transformed into the corresponding homologous carboxylic acid by treatment with Fe0/CO/O2 or Cu0/CO/O2 in pyridine/acetic acid. Mechanistic studies support a reaction pathway involving the insertion of CO into a carbon-iron or carbon-copper bond.

引用

收藏

页码：4389 / 4392

页数：4

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