AUTOXIDATION OF TRIS(TRIMETHYLSILYL)SILANE

被引：44

作者：

CHATGILIALOGLU, C ^{[1
]}

GUARINI, A ^{[1
]}

GUERRINI, A ^{[1
]}

SECONI, G ^{[1
]}

机构：

[1] IST GUIDO DONEGANI SPA,I-28100 NOVARA,ITALY

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 08期

关键词：

D O I：

10.1021/jo00034a001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tris(trimethylsilyl)silane reacts spontaneously at ambient temperature with molecular oxygen to form (Me3SiO)2Si(H)SiMe3 in high yield. The reaction proceeds via a free-radical chain mechanism and probably involves three consecutive unimolecular processes which are unknown in the literature.

引用

收藏

页码：2207 / 2208

页数：2

相关论文

共 11 条

[1] REACTIONS OF TRIS(TRIMETHYLSILYL)SILYL RADICALS WITH NITROALKANES - EPR, KINETIC, AND PRODUCT STUDIES [J].

BALLESTRI, M ;

CHATGILIALOGLU, C ;

LUCARINI, M ;

PEDULLI, GF .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (03) :948-952

[2] ELECTRON-SPIN RESONANCE STUDY OF SOME GROUP IVB ORGANOMETALLIC PEROXY RADICALS [J].

BENNETT, JE ;

HOWARD, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (23) :8244-&

[3]

BUERGER H, 1969, J ORGANOMET CHEM, V18, P299

[4]

CHATGILIALOGLU C, IN PRESS ACC CHEM RE

[5] A STUDY OF ORGANOSILICON FREE RADICALS [J].

CURTICE, J ;

GILMAN, H ;

HAMMOND, GS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (17) :4754-4759

[6]

DOHMARU T, 1988, CHEM KINETICS SMALL, V3, P165

[7] 1,2-MIGRATION OF THE TRIMETHYLSILYL GROUP IN FREE-RADICALS [J].

HARRIS, JM ;

MACINNES, I ;

WALTON, JC ;

MAILLARD, B .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 403 (03) :C25-C28

[8] ORGANOMETALLIC PEROXY-RADICALS .5. TRIALKYLSILYLPEROXY AND TRIALKYLSTANNYLPEROXY RADICALS [J].

HOWARD, JA ;

TAIT, JC ;

TONG, SB .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1979, 57 (20) :2761-2766

[9]

MARCH J, 1985, ADV ORGANIC CHEM

[10] BOND-DISSOCIATION ENERGY VALUES IN SILICON-CONTAINING COMPOUNDS AND SOME OF THEIR IMPLICATIONS [J].

WALSH, R .

ACCOUNTS OF CHEMICAL RESEARCH, 1981, 14 (08) :246-252