A GENERALIZED FORM OF THE KISSINGER EQUATION

被引:69
作者
CHEN, D [1 ]
GAO, X [1 ]
DOLLIMORE, D [1 ]
机构
[1] UNIV TOLEDO,COLL PHARM,TOLEDO,OH 43606
关键词
D O I
10.1016/0040-6031(93)80085-O
中图分类号
O414.1 [热力学];
学科分类号
摘要
An equation is deduced in this paper and an attempt is made to obtain the peak maxima information theoretically from the differential thermogravimetry curves. The calculations are critically assessed. The Kissinger method, which also deals with the peak maxima, is also discussed. A comparison of the equation due to Kissinger and that of the equation deduced in this paper shows that the Kissinger equation is a special case of this equation. The approximation made in the deduction of the Kissinger equation can be restated as ''The extent of reaction at the peak maxima under different heating rates is the same.''
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页码:109 / 117
页数:9
相关论文
共 3 条
[1]  
CHEN D, 1992, ANAL INSTRUM, V20, P137
[2]  
KISSINGER HE, 1957, ANAL CHEM, V29, P1702, DOI DOI 10.1021/AC60131A045
[3]   A NEW METHOD OF ANALYZING THERMOGRAVIMETRIC DATA [J].
OZAWA, T .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1965, 38 (11) :1881-+