LIQUID-LIQUID EQUILIBRIA IN SOME BINARY AND TERNARY MIXTURES WITH TETRAETHYLENE GLYCOL

被引:9
作者
ALQATTAN, MA
ALSAHHAF, TA
FAHIM, MA
机构
[1] UNITED ARAB EMIRATES UNIV,DEPT CHEM & PETR ENGN,AL AIN,U ARAB EMIRATES
[2] UNIV KUWAIT,DEPT CHEM ENGN,SAFAT 13060,KUWAIT
关键词
D O I
10.1021/je00013a030
中图分类号
O414.1 [热力学];
学科分类号
摘要
Liquid-liquid equilibria (LLE) for tetraethylene glycol + heptane or + decalin and tetraethylene glycol + decane, + benzene, or + ethylbenzene over a temperature range of 293-330.5 K were used to estimate the interaction parameters between a new solvent group (tetraethylene glycol) and the main groups of CH2 (paraffinic > CH2), ACH (aromatic greater than or equal to CH), ACCH(2) (aromatic CCH2) and CHNA (condensed naphthenic CH)as a function of temperature. The estimated interaction parameters of these groups have been used with other interaction parameters present in the literature to compare calculated values with the experimental LLE equilibrium measurements.
引用
收藏
页码:111 / 113
页数:3
相关论文
共 4 条
[1]  
ALQATTAN MA, 1991, THESIS U KUWAIT
[2]  
Fredenslund A, 1977, VAPOR LIQUID EQUILIB
[3]   LIQUID-LIQUID EQUILIBRIUM DATA - THEIR RETRIEVAL, CORRELATION AND PREDICTION .3. PREDICTION [J].
MAGNUSSEN, T ;
SORENSEN, JM ;
RASMUSSEN, P ;
FREDENSLUND, A .
FLUID PHASE EQUILIBRIA, 1980, 4 (1-2) :151-163
[4]   SOLVENT-EXTRACTION OF AROMATICS FROM MIDDLE DISTILLATES - EQUILIBRIA PREDICTION METHOD BY GROUP CONTRIBUTION [J].
RAHMAN, M ;
MIKITENKO, P ;
ASSELINEAU, L .
CHEMICAL ENGINEERING SCIENCE, 1984, 39 (11) :1543-1558