SYNTHESIS OF BIS-CYCLOMETALLATING N-C-N HEXADENTATE LIGANDS VIA C-C AROMATIC COUPLINGS AND THEIR DINUCLEAR RUTHENIUM(II) COMPLEXES

被引：54

作者：

BELEY, M

CHODOROWSKI, S

COLLIN, JP

SAUVAGE, JP

机构：

[1] Laboratoire de Chimie Organo-Minérale, associé au CNRS, Faculteé de Chimie, 1, rue Blaise Pascal

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 18期

关键词：

D O I：

10.1016/S0040-4039(00)60485-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By combining palladium catalyzed C-C coupling procedures either based on aromatic stannanes or utilizing boronic acids or esters (Suzuki's reaction), various bis-cyclometallating N-C-N ligands could be prepared. Their di-ruthenium(II) complexes have also been synthesized.

引用

收藏

页码：2933 / 2936

页数：4

相关论文

共 13 条

[1] SOLVOLYSIS OF 2-PYRIDYLTRIMETHYL-SILANE -GERMANE AND -STANNANE BY ALCOHOLS AND BY WATER [J].

ANDERSON, DG ;

WEBSTER, DE .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1968, (07) :765-&

[2]

ASHWELL GJ, 1991, MOL ELECTRONICS

[3] UNSYMMETRICAL HETEROBIARYL SYNTHESIS - A HIGHLY EFFICIENT PALLADIUM-CATALYZED CROSS-COUPLING REACTION OF HETEROARYL TRIALKYLSTANNANES WITH ARYL HALIDES [J].

BAILEY, TR .

TETRAHEDRON LETTERS, 1986, 27 (37) :4407-4410

[4] 3,3',5,5'-TETRAPYRIDYLBIPHENYL - A BISCYCLOMETALATING BRIDGING LIGAND WITH A HIGH COUPLING ABILITY IN RU(III),RU(II) MIXED-VALENCE SYSTEMS [J].

BELEY, M ;

COLLIN, JP ;

LOUIS, R ;

METZ, B ;

SAUVAGE, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (22) :8521-8522

[5] THE DIRECTED SYNTHESIS OF BIARYL COMPOUNDS - MODERN CONCEPTS AND STRATEGIES [J].

BRINGMANN, G ;

WALTER, R ;

WEIRICH, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (09) :977-991

[6] EXPEDIENT ROUTE TO 3-SUBSTITUTED AND 3,3'-SUBSTITUTED 1,1'-BI-2-NAPHTHOLS BY DIRECTED ORTHO METALATION AND SUZUKI CROSS COUPLING METHODS [J].

COX, PJ ;

WANG, W ;

SNIECKUS, V .

TETRAHEDRON LETTERS, 1992, 33 (17) :2253-2256

[7] BISUBSTRATE REACTION TEMPLATES - EXAMINATION OF THE CONSEQUENCES OF IDENTICAL VERSUS DIFFERENT BINDING-SITES [J].

KELLY, TR ;

BRIDGER, GJ ;

ZHAO, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (22) :8024-8034

[8] WATER-SOLUBLE HYPERBRANCHED POLYPHENYLENE - A UNIMOLECULAR MICELLE [J].

KIM, YH ;

WEBSTER, OW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (11) :4592-4593

[9] SYNTHESIS AND CHARACTERIZATION OF A SERIES OF MONODISPERSE, 1,3,5-PHENYLENE-BASED HYDROCARBON DENDRIMERS INCLUDING C276H186 AND THEIR FLUORINATED ANALOGS [J].

MILLER, TM ;

NEENAN, TX ;

ZAYAS, R ;

BAIR, HE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (03) :1018-1025

[10] THE PALLADIUM-CATALYZED CROSS-COUPLING REACTION OF PHENYLBORONIC ACID WITH HALOARENES IN THE PRESENCE OF BASES [J].

MIYAURA, N ;

YANAGI, T ;

SUZUKI, A .

SYNTHETIC COMMUNICATIONS, 1981, 11 (07) :513-519