DIRECT ARYLATION OF FERROCENYLACETYLENES AND FERROCENYLETHENES UNDER AUTOCATALYTIC MEERWEIN CONDITIONS

被引：19

作者：

NOCK, H ^{[1
]}

SCHOTTENBERGER, H ^{[1
]}

机构：

[1] LEOPOLD FRANZENS UNIV INNSBRUCK,INST ALLGEMEINE ANORGAN & THEORET CHEM,INNRAIN 52A,A-6020 INNSBRUCK,AUSTRIA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 25期

关键词：

D O I：

10.1021/jo00077a024

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ferrocenylacetylene reacts with arenediazonium in various solvents to form (arylethynyl)ferrocenes and, depending on the solvent composition, the corresponding Meerwein-type arylethenes. Applied to vinylferrocene, this autocatalytic reaction even leads to double arylation Ferrocenyl-yne-ene systems, however, give rise to radical quenching on the olefinic moiety with partial arylation.

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收藏

页码：7045 / 7048

页数：4

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