COMPOSITION-TUNABLE METAL-ALKYL XEROGELS AS PRECURSORS FOR HOMOGENEOUSLY DISPERSED METALS IN AMORPHOUS SILICA MATRIX

被引：13

作者：

BRAUNSTEIN, P ^{[1
]}

CAUZZI, D ^{[1
]}

PREDIERI, G ^{[1
]}

TIRIPICCHIO, A ^{[1
]}

机构：

[1] UNIV PARMA,DIPARTIMENTO CHIM GEN & INORGAN,I-43100 PARMA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 02期

关键词：

D O I：

10.1039/c39950000229

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Organometallic alkyls of Fe, Mo and W containing an -Si(OEt)3 function are prepared and used for the synthesis of metal containing inorganic-organometallic hybrid materials by set-gel processing with Si(OEt)(4).

引用

页码：229 / 230

页数：2

共 18 条

[1]

BRAUNSTEIN P, 1988, STEREOCHEMISTRY ORGA, V3

[2] METAL-COMPLEXES IN INORGANIC MATRICES .7. NANOMETER-SIZED, UNIFORM METAL PARTICLES IN A SIO2 MATRIX BY SOL-GEL PROCESSING OF METAL-COMPLEXES [J].

BREITSCHEIDEL, B ;

ZIEDER, J ;

SCHUBERT, U .

CHEMISTRY OF MATERIALS, 1991, 3 (03) :559-566

[3] HYDROGENATION AND HYDROSILYLATION ACTIVITY OF HOMOGENEOUS AND IMMOBILIZED DICARBONYL(2,4-PENTANEDIONATO)RHODIUM COMPLEXES [J].

CAPKA, M ;

CZAKOOVA, M ;

URBANIAK, W ;

SCHUBERT, U .

JOURNAL OF MOLECULAR CATALYSIS, 1992, 74 (1-3) :335-344

[4]

CAUZZI D, IN PRESS J ORGANOMET

[5] ANCHORING METAL SPECIES ON A THIOUREA-FUNCTIONALIZED SILICA XEROGEL - INSITU PRODUCTION OF COLLOIDAL PALLADIUM PARTICLES [J].

FERRARI, C ;

PREDIERI, G ;

TIRIPICCHIO, A ;

COSTA, M .

CHEMISTRY OF MATERIALS, 1992, 4 (02) :243-245

[6]

Gates B.C., 1986, METAL CLUSTERS CATAL

[7] SYNTHESIS AND INCORPORATION OF 4-TRIETHOXYSILYL-1,2-BIS(DIPHENYLPHOSPHINO)BENZENE INTO SILICA-GEL AND SOLGEL POLYMERS - PREPARATION AND UTILIZATION OF RECYCLABLE CATALYSTS FOR ALKENE HYDROFORMYLATION AND METHANOL HOMOLOGATION [J].

HARDEE, JR ;

TUNNEY, SE ;

FRYE, J ;

STILLE, JK .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1990, 28 (13) :3669-3684

[8] THE SOL-GEL PROCESS [J].

HENCH, LL ;

WEST, JK .

CHEMICAL REVIEWS, 1990, 90 (01) :33-72

[9]

HENCH LL, 1994, NEW J CHEM, V18, P989

[10] A NEW SILICA-SUPPORTED PLATINUM AMINE CATALYST FOR THE REACTION OF SILANES WITH ALCOHOLS [J].

HILAL, HS ;

RABAH, A ;

KHATIB, IS ;

SCHREINER, AF .

JOURNAL OF MOLECULAR CATALYSIS, 1990, 61 (01) :1-17

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