PHOTO-CHEMICAL HOLE-BURNING IN VIBRONIC BANDS OF THE S1]-S0 TRANSITION OF FREE-BASE PORPHIN IN AN NORMAL-OCTANE CRYSTAL

被引：39

作者：

VOELKER, S

MACFARLANE, RM

机构：

[1] IBM Research Laboratory, San Jose

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 61卷 / 03期

关键词：

D O I：

10.1016/0009-2614(79)87141-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The homogeneous linewidths of vibronic bands of the S1 ← S0 transition of free-base porphin (H2P) in an n-octane crystal at 4.2 K have been measured by photochemical hole-burning. Fourteen single vibronic levels were selectively excited in a 1600 cm-1 region above the origin. The holewidths vary strongly (by a factor of ≈ 40) as a function of the particular vibration excited and do not increase monotonically with energy. © 1979.

引用

页码：421 / 425

页数：5

共 19 条

[1] ANISOTROPY OF LIGHT-EMISSION AND ABSORPTION BY PORPHIN MOLECULES IN N-OCTANE SINGLE-CRYSTALS [J].

ARABEI, SM ;

SHKIRMAN, SF ;

SOLOVYOV, KN ;

YEGOROVA, GD .

SPECTROSCOPY LETTERS, 1977, 10 (09) :677-697

[2]

BOESL V, 1975, CHEM PHYS LETT, V31, P7

[3]

BURGER H, 1975, PORPHYRINS METALLOPO, pCH11

[4]

GLADKOV LL, 1976, ZH PRIKL SPEKTROSK, V25, P94

[5] HOMOGENEOUS, PURE ELECTRONIC LINEWIDTH IN SPECTRUM OF A PHTHALOCYANINE-H-2 SOLUTION IN NORMAL-OCTANE AT 5K [J].

GOROKHOVSKI, AA ;

KAARLI, R ;

REBANE, LA .

OPTICS COMMUNICATIONS, 1976, 16 (02) :282-284

[6]

GOROKHOVSKII AA, 1974, JETP LETT+, V20, P216

[7]

Gradyushko A. T., 1977, Optics and Spectroscopy, V43, P37

[8]

GRADYUSHKO AT, 1975, OPT SPECTROSC, V30, P137

[9]

HOCHSTRASSER RM, 1973, EXCITED STATES, P120

[10]

JANSEN G, 1977, THESIS U LEYDEN

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