SYNTHESIS OF PHOSPHINITE DERIVATIVES OF SUGARS - APPLICATION TO METHYL PENTA-2,4-DIENOATE CYCLODIMERIZATION, PENTOLACTONE HYDROGENATION AND HYDROSILYLATION

被引:15
作者
BENDAYAN, A
MASOTTI, H
PEIFFER, G
SIV, C
ARCHAVLIS, A
机构
[1] UNIV MARSEILLE 3,ORGANO PHOSPHORES LAB,URA 1409,AVE ESCADRILLE,BP 552,F-13397 MARSEILLE 13,FRANCE
[2] UNIV MARSEILLE 3,ENSSPICAM,F-13397 MARSEILLE 13,FRANCE
关键词
D O I
10.1016/0022-328X(93)83052-W
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Sugar-derived phosphinites, when used as ligands in the catalytic hydrogenation of alpha-ketopentolactone, lead to the corresponding alcohol with a better enantiomeric excess (20%) than in hydrosilylation (10%). In the cyclodimerisation of penta-2,4-dienoic acid methyl ester they lead to the meso cycloocta-3,7-diene-1,2-doic dimethyl ester.
引用
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页码:41 / 46
页数:6
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