SYNTHESIS OF CHROMONES AND THIOCHROMONES (4H-BENZO=B'THIAPYRONES. FROM ENAMINES

被引:13
作者
BOYD, GV
HEWSON, D
NEWBERRY, RA
机构
来源
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 06期
关键词
D O I
10.1039/j39690000935
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Fourteen 2,3-cycloalkeno-chromones and -thiochromones (4H-benzo[b] thiapyrones) have been prepared by a new method in which enamines of cyclic ketones are condensed with the mixed anhydrides formed from ethyl chloroformate and acetylsalicylic acids and their thio-analogues. An acyl migration occurs in the reactions of 2-pyrrolidinopropene to give 3-acyl-2-methylchromones.
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页码:935 / &
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