LANTHANIDE ION-EXCHANGE IN SODIUM-BETA-ALUMINA

被引：19

作者：

TIETZ, F ^{[1
]}

URLAND, W ^{[1
]}

机构：

[1] SONDERFORSCH BEREICH 173,W-3000 HANNOVER 1,GERMANY

来源：

SOLID STATE IONICS | 1991年 / 46卷 / 3-4期

关键词：

D O I：

10.1016/0167-2738(91)90234-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Single crystals of Na+-beta-alumina have been exchanged by rare-earth ions (Pr3+, Nd3+, Ho3+) using molten lanthanide trichlorides. Chemical analysis revealed exchange rates up to 95% for the sodium ions. Powder X-ray photographs showed a decrease of the c lattice parameter of about 0.1 angstrom for nearly completely exchanged samples.

引用

页码：331 / 335

页数：5

共 16 条

[11]

Meyer G., 1989, INORG SYNTH, V25, P146

[12] REFINEMENT OF STRUCTURE OF SODIUM BETA-ALUMINA [J].

PETERS, CR ;

BETTMAN, M ;

MOORE, JW ;

GLICK, MD .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1971, B 27 (SEP15) :1826-&

[13]

ROTH WL, 1976, SUPERIONIC CONDUCT, P00223, DOI DOI 10.1007/978-1-4615-8789-7_33

[14] CZOCHRALSKI GROWTH OF SINGLE-CRYSTAL SODIUM BETA-ALUMINA [J].

ROTHROCK, LR .

JOURNAL OF CRYSTAL GROWTH, 1977, 39 (01) :180-184

[15] SYNTHESIS OF DIVALENT AND TRIVALENT BETA''-ALUMINAS BY ION-EXCHANGE [J].

SATTAR, S ;

GHOSAL, B ;

UNDERWOOD, ML ;

MERTWOY, H ;

SALTZBERG, MA ;

FRYDRYCH, WS ;

ROHRER, GS ;

FARRINGTON, GC .

JOURNAL OF SOLID STATE CHEMISTRY, 1986, 65 (02) :231-240

[16]

TIETZ F, 1991, MAY INT WORKSH BET A

← 1 2 →