CIRCULAR-DICHROISM OF SOME 2-(PHENYLMETHYL)PYRIDINE DERIVATIVES

被引:2
作者
BEROVA, N
BOJADZIEV, S
BRESCIANIPAHOR, N
IVANOV, PM
KOJICPRODIC, B
RAKOVSKA, R
RUZICTOROS, Z
SNATZKE, G
机构
[1] RUHR UNIV BOCHUM, LEHRSTUHL STRUKT CHEM, POSTFACH 102148, W-4630 BOCHUM, GERMANY
[2] RUDJER BOSKOVIC INST, YU-41001 ZAGREB, YUGOSLAVIA
[3] BULGARIAN ACAD SCI, INST ORGAN CHEM, CTR BIOCHEM, BU-1113 SOFIA, BULGARIA
[4] UNIV TRIESTE, DIPARTIMENTO SCI CHIM, I-34127 TRIESTE, ITALY
关键词
D O I
10.1002/hlca.19900730707
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The absolute configuration of the 2‐(phenylmethyl)pyridine derivatives 1–9 had been established by X‐ray diffraction and chemical correlation. Their CD spectra have been studied in different solvents for the free and protonated forms. It has now been found that, from the sign of the strong CD couplet between 270 and 220 nm, which was observable for all these compounds besides 7 and 9, their absolute configuration can be determined much quicker. Copyright © 1990 Verlag GmbH & Co. KGaA, Weinheim
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页码:1853 / 1860
页数:8
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