IONIC INTERACTIONS IN MCF3SO3-POLYETHER COMPLEXES CONTAINING MONOVALENT, DIVALENT AND TRIVALENT CATIONS

被引：72

作者：

PETERSEN, G

TORELL, LM

PANERO, S

SCROSATI, B

DASILVA, CJ

SMITH, M

机构：

[1] UNIV ROMA LA SAPIENZA,DIPARTIMENTO CHIM,I-00185 ROME,ITALY

[2] UNIV MINHO,DEPT CHEM,P-4719 BRAGA,PORTUGAL

来源：

SOLID STATE IONICS | 1993年 / 60卷 / 1-3期

关键词：

D O I：

10.1016/0167-2738(93)90274-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ion association has been investigated by Raman scattering from triflate salts M (CF3SO3)x in PEO (400) for various cationic substitutions (M=Li+, Ca2+, Cu2+, and Nd3+) and for OH-capped, respectively CH3-Capped, polymer chains. The ion-ion interaction shows different temperature behavior in different systems. The observations are discussed in terms of recent theories which consider volume changes (electrostriction) in the salt dissociation process.

引用

页码：55 / 60

页数：6

共 14 条

[1] A COMPUTATIONAL AND EXPERIMENTAL-STUDY ON THE JAHN-TELLER EFFECT IN THE HYDRATED COPPER(II) ION - COMPARISONS WITH HYDRATED NICKEL(II) IONS IN AQUEOUS-SOLUTION AND SOLID TUTTONS SALTS [J].