PREPARATION AND STRUCTURAL CHARACTERIZATION OF CATIONIC DINUCLEAR RUTHENIUM(II) - THIOLATE COMPLEXES, [RU2(SPH)3(ETA-6-PARA-CYMENE)2]Y (Y=CL AND PF6)

被引:30
作者
MASHIMA, K [1 ]
MIKAMI, A [1 ]
NAKAMURA, A [1 ]
机构
[1] OSAKA UNIV, FAC SCI, DEPT MACROMOLEC SCI, TOYONAKA, OSAKA 560, JAPAN
关键词
D O I
10.1246/cl.1992.1795
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Treatment of [RuCl2(p-cymene)]2 with sodium benzenethiolate in methanol afforded a cationic dinuclear ruthenium thiolate complexes, [Ru2(SPh)3(P-cymene)2]Y (2a Y = Cl; 2b: Y = PF6), whose structure is determined by X-ray analysis of 2b.
引用
收藏
页码:1795 / 1798
页数:4
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