PREPARATION AND STRUCTURAL CHARACTERIZATION OF CATIONIC DINUCLEAR RUTHENIUM(II) - THIOLATE COMPLEXES, [RU2(SPH)3(ETA-6-PARA-CYMENE)2]Y (Y=CL AND PF6)

被引：30

作者：

MASHIMA, K ^{[1
]}

MIKAMI, A ^{[1
]}

NAKAMURA, A ^{[1
]}

机构：

[1] OSAKA UNIV, FAC SCI, DEPT MACROMOLEC SCI, TOYONAKA, OSAKA 560, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 09期

关键词：

D O I：

10.1246/cl.1992.1795

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of [RuCl2(p-cymene)]2 with sodium benzenethiolate in methanol afforded a cationic dinuclear ruthenium thiolate complexes, [Ru2(SPh)3(P-cymene)2]Y (2a Y = Cl; 2b: Y = PF6), whose structure is determined by X-ray analysis of 2b.

引用

页码：1795 / 1798

页数：4

共 22 条

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[8] INTRAMOLECULAR DYNAMICS IN THE MIXED-VALENCE CLUSTER (CH3C5H4)4RU4S4(2+) - OBSERVATION OF MOBILE METAL-METAL BONDS
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[10] SYNTHESIS AND REACTIVITY OF (PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM BIS(THIOLATE) AND THIOLATE HYDRIDE COMPLEXES
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