CHARACTERIZATION OF HIGH-VALENT IRON PORPHYRIN IN CATALYTIC REACTION BY IRON(III) TETRAPENTAFLUOROPHENYLPORPHYRIN

被引：39

作者：

FUJII, H ^{[1
]}

机构：

[1] HOKKAIDO UNIV, FAC SCI, DEPT CHEM, SAPPORO, HOKKAIDO 060, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 08期

关键词：

D O I：

10.1246/cl.1994.1491

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High valent species formed from iron(III) meso-tetra-(pentafluorophenyl)porphyrin was first prepared in dichloromethane and characterized by low-temperature UV-vis absorption spectra, proton NMR and ESR. These measurements showed the formation of oxo iron(IV) porphyrin pi-cation radical, not iron(V) porphyrin.

引用

页码：1491 / 1494

页数：4

共 14 条

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