DEHYDRATION OF N-BUTANOL OVER HIGHLY DISPERSED HETEROPOLYACID INTERCALATION COMPOUNDS

被引：8

作者：

HASHIMOTO, K ^{[1
]}

MATSUMURA, Y ^{[1
]}

FUKUCHI, M ^{[1
]}

KERA, Y ^{[1
]}

机构：

[1] KINKI UNIV,FAC SCI & ENGN,DEPT APPL CHEM,OSAKA,OSAKA 577,JAPAN

来源：

CATALYSIS LETTERS | 1993年 / 19卷 / 04期

关键词：

HETEROPOLYACID; DEHYDRATION; INTERCALATE; PYRIDINE; BUTANOL;

D O I：

10.1007/BF00767081

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Heteropolyacid is introduced in an intercalation compound of zinc aluminum carbonate hydroxide by an anion-exchanging technique. The acid is probably present as H2.1PW9.2O33.34.2- and is shown to be highly dispersed. The compound catalyzes dehydration of n-butanol with noticeably higher activity and selectivity to 1-butene than free Keggin type 12-heteropolyacid.

引用

页码：375 / 381

页数：7

共 23 条

[1]

ALLMANN R, 1968, AM MINERAL, V53, P1057

[2] ACID-BASE AND OXIDATION CATALYSIS ON HETEROPOLYSALTS WITH SURFACE ACID LAYERS [J].

BRUCKMAN, K ;

HABER, J ;

SERWICKA, EM .

FARADAY DISCUSSIONS, 1989, 87 :173-187

[3] LASER RAMAN AND DTA/TGA STUDY OF H3+NPVNMO12-NO40 HETEROPOLYACIDS PURE AND SUPPORTED ON K3PMO12O40 [J].

BRUCKMAN, K ;

HABER, J ;

SERWICKA, EM ;

YURCHENKO, EN ;

LAZARENKO, TP .

CATALYSIS LETTERS, 1990, 4 (02) :181-190

[4] THE INFRARED SPECTRA OF SOME SIMPLE AND COMPLEX CARBONATES [J].

GATEHOUSE, BM ;

LIVINGSTONE, SE ;

NYHOLM, RS .

JOURNAL OF THE CHEMICAL SOCIETY, 1958, (SEP) :3137-3142

[5] ALUMINA-CATALYZED CLEAVAGE OF ETHERS AND THERMAL DECOMPOSITION OF ALUMINUM ALKOXIDES [J].

HEIBA, EAI ;

LANDIS, PS .

JOURNAL OF CATALYSIS, 1964, 3 (06) :471-476

[6] THE INTERACTION OF CESIUM IONS WITH SILICA-SUPPORTED 12-MOLYBDOPHOSPHORIC ACID [J].

KASZTELAN, S ;

PAYEN, E ;

MOFFAT, JB .

JOURNAL OF CATALYSIS, 1991, 128 (02) :479-486

[7]

KASZTELAN S, 1989, J CATAL, V125, P3195

[8] NEW CHEMISTRY FOR HETEROPOLYANIONS IN ANHYDROUS NONPOLAR-SOLVENTS - COORDINATIVE UNSATURATION OF SURFACE ATOMS - POLYANION OXYGEN CARRIERS [J].

KATSOULIS, DE ;

POPE, MT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (09) :2737-2738

[9] The structure and formula of 12-phosphotungstic acid. [J].

Keggin, JF .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-CONTAINING PAPERS OF A MATHEMATICAL AND PHYSICAL CHARACTER, 1934, 144 (A851) :0075-0100

[10] ANIONS OF THE TYPE (RMOH2)3W18P2O689- AND [H2OCO]3W18P2O6812- - A REINVESTIGATION OF B,BETA-W9PO349- [J].

KNOTH, WH ;

DOMAILLE, PJ ;

FARLEE, RD .

ORGANOMETALLICS, 1985, 4 (01) :62-68

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