STEREOCHEMICAL CONTROL IN THE OXYMERCURATION OF 5-ALKEN-1-OLS

被引：48

作者：

TIUS, MA

BUSCH-PETERSEN, J

机构：

[1] Department of Chemistry, University of Hawaii, Honolulu, HI 96822

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 29期

关键词：

D O I：

10.1016/S0040-4039(00)77058-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The axial preference which had been observed during the intramolecular reaction of cannabinoid precursors 2 and 3 is not a heteroatom-mediated directing effect. Rather, it reflects a kinetic preference which may be related to the anomeric effect.

引用

页码：5181 / 5184

页数：4

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