ADDITION OF NITRYL IODIDE TO OLEFINS

被引：65

作者：

HASSNER, A

KROPP, JE

KENT, GJ

机构：

[1] Department of Chemistry, University of Colorado, Boulder

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 09期

关键词：

D O I：

10.1021/jo01261a030

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of silver nitrite with iodine in the presence of olefins was studied and was found to lead to nitroiodo adducts. The reaction has the characteristics of a nitryl iodide addition and appears to proceed by a free-radical attack of an NO2 species on the double bond. Stereochemical and regiochemical considerations are discussed. The method provides a selective synthesis of β-iodonitro-, vinylnitro-, and nitroalkanes under mild reaction conditions. © 1969, American Chemical Society. All rights reserved.

引用

页码：2628 / &

共 28 条

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