GEOMETRY AND ELECTRONIC STRUCTURE OF SUBSTITUTED SCHIFFS BASES

被引：45

作者：

HOULDEN, SA

CSIZMADI.IG

机构：

[1] Department of Chemistry, Lash Miller Chemical Laboratories University of Toronto, Toronto 5, Ont.

来源：

TETRAHEDRON | 1969年 / 25卷 / 05期

关键词：

D O I：

10.1016/S0040-4020(01)82687-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

One electron Extended Hückel Molecular Orbital (EHMO) theory has been used to study the conformational geometry of five benzal-p-X-aniline (X = H, Me3, Cl, Br, Me3O) Schiff's bases. The electronic structure predicted by this method was used as a guide for a least squares resolution of the observed electronic (UV) spectra. The resultant resolved spectra are discussed in terms of correlations of band shifts with substituent properties. © 1969.

引用

页码：1137 / &

共 43 条

[1] EXTENDED HUCKEL THEORY AND SHAPE OF MOLECULES [J].