O-2 MOLECULE ION IN CAF2 - STRUCTURE AND DYNAMICAL FEATURES

被引:20
作者
BILL, H
机构
[1] Department of Physical Chemistry, Sciences II, University
关键词
D O I
10.1063/1.437243
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This experimental study reports EPR and ENDOR results of an O 2- molecule ion in natural yellow fluorites. The O 2- is associated with a sodium neighbor and a calcium neighbor. This cluster performs a rapid switching movement between energetically equivalent positions. The resulting dynamical features in the EPR spectrum are investigated with the aid of the stochastic Liouville equation. © 1979 American Institute of Physics.
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页码:277 / 283
页数:7
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