A SOLUTION OF THE GAUGE-ORIGIN PROBLEM FOR THE MAGNETIC SHIELDING CONSTANT

被引：52

作者：

GEERTSEN, J

机构：

[1] Department of Chemistry, Odense University

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 179卷 / 5-6期

关键词：

D O I：

10.1016/0009-2614(91)87090-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It is shown that the diamagnetic contribution to the magnetic shielding constant can be expressed in terms of the polarization propagator. Contrary to the commonly used approach, the suggested method gives a result for the total shielding which is independent of the origin chosen for the vector potential.

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页码：479 / 482

页数：4

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