KINETIC AND EQUILIBRIUM STUDIES OF THE REACTION OF 2,4-DINITROPHENYL-2,4,6-TRINITROPHENYLMETHANE WITH CRYPTANDS IN ACETONITRILE

被引：6

作者：

BRZEZINSKI, B

JARCZEWSKI, A

LESKA, B

SCHROEDER, G

机构：

[1] Faculty of Chemistry, Adam Mickiewicz University, 60-780 Poznań

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1994年 / 318卷

关键词：

D O I：

10.1016/0022-2860(93)07900-H

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Deprotonation of 2,4-dinitrophenyl-2,4,6-trinitrophenylmethane (C-acid) by five cryptands, 221, 222, 222B, 22 and di(Ph-CH2)22, in acetonitrile has been studied by visible and H-1 NMR spectroscopy. The reaction of C-acid with the cryptands in acetonitrile solution gives a stable, asymmetric carbanion and a protonated base. Kinetic and equilibrium measurements for reactions of C-acid with five cryptands have been completed.

引用

页码：107 / 112

页数：6

共 22 条

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[2]

BREZEZINSKI B, 1992, J CHEM SOC P2, V2, P2257

[3] KINETIC AND EQUILIBRIUM STUDIES OF THE PROTON AND DEUTERON TRANSFER-REACTION BETWEEN BIS(2,4-DINITROPHENYL)METHANE AND STRONG NITROGEN BASES IN ACETONITRILE [J].