C-HE-AR VARIATIONS WITHIN A DUNITE NODULE AS A FUNCTION OF FLUID INCLUSION MORPHOLOGY

Combined laser extraction and manometric-quadrupole-mass spectroscopic measurements permit the simultaneous analysis of CO2, He and Ar in selected fluid inclusion generations trapped in a dunite nodule from Reunion Island. Variations in Ar-40/Ar-36 in primary fluid inclusions (1000-8500) implies that atmospheric Ar is present in all the trapped fluids, possibly introduced by percolation of seawater into the magma from which the olivine crystallised. Later inclusion generations have lower Ar-40/Ar-36 (500-3500). CO2/He-3 ratios ((1-9.6) x 10(9)) are at the lower range of reported values from high He-3/He-4 xenoliths ((1-20) x 10(9)) but show no systematic variation with inclusion generation. He-4/Ar-4 double dagger values are constant (2.4 +/- 0.1) for all inclusion generations and over wide ranges in CO2/He ((0.2-8.2) x 10(5)). This is not consistent with the relative solubilities of CO2, He and Ar in basaltic melts but implies that f(CO2) is determined by some other process, possibly the partitioning of CO2 into an immiscible phase. Mixing between high He-3/He-4, high He abundance mantle (primitive He mantle) with a degassed and incompatible element enriched component can generate the coupled high He-3/He-4-radiogenic Sr and Pb isotopic compositions of Reunion lavas. The range in C/He-3 likely for the primitive He mantle ((1-20)x 10(9)) spans the estimated C/He-3 of chondrites (approximate to 2 x 10(9)). The primitive He component cannot represent undegassed primitive mantle as the C/Ar-36 values of Reunion (> 1 x 10(9)) are higher than those of chondrites (8 X 10(7)).