CAGE EXPANSION OF [((CYNLI)(3)SB)(2)] - SYNTHESIS AND STRUCTURE OF THE TRIMETALLIC COMPLEX [((CYNLI)(3)SB)(2)(TBUOK)(3)-CENTER-DOT-X-C6H5CH3]

被引:23
作者
BARR, D
EDWARDS, AJ
PAVER, MA
RAITHBY, PR
RENNIE, MA
RUSSELL, CA
WRIGHT, DS
机构
[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND
[2] ASSOCIATED OCTEL CO,WIRRAL,CHESHIRE,ENGLAND
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 09期
关键词
ANTIMONY COMPOUNDS; CAGE COMPOUNDS; LITHIUM COMPOUNDS; POTASSIUM COMPOUNDS;
D O I
10.1002/anie.199510121
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cut in half, add the plane, and sandwich together. In effect these steps form the twenty‐membered cage Sb2N6Li6K3O3 from Sb2N6Li6 and KotBu (see below, the cyclohexyl groups on the N atoms and the tBu groups on the O atoms have been omitted for clarity). The driving force is probably provided by the formation of LiO bonds. The apices of both polyhedra are Sb atoms bound to the N atoms that are linked by the Li atoms. In the center of the right‐hand polyhedron is the K3O3 plane. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
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页码:1012 / 1013
页数:2
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