OXYGEN ACTIVATION WITH TRANSITION-METAL COMPLEXES - NICKEL-CATALYZED OXIDATION OF A PENTACOORDINATED SUBSTRATE

被引：29

作者：

BERKESSEL, A

BATS, JW

SCHWARZ, C

机构：

[1] Institut Für Organische Chemie, Universität Frankfurt, D-6000, Niederurseler Hang

[2] Max-Planck-Institut Für Festkörperforschung, Stuttgart, D‐7000

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 01期

关键词：

D O I：

10.1002/anie.199001061

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidative degradation of the pentadentate ligand is observed when rac‐1 is allowed to react with O2, in solution. The products are 2, formaldehyde, and diphenyl disulfide. The first step of the reaction is most likely an addition of O2, to the Ni center, since solid rac‐1, in which the sixth coordination site of the Ni atom is occupied by an O atom of a second molecule of 1, is inert towards O2. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：106 / 108

页数：3

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