NUCLEAR-QUADRUPOLE INTERACTION OF HG-199M MERCAPTIDES

被引：11

作者：

BUTZ, T ^{[1
]}

VOLKEL, T ^{[1
]}

NUYKEN, O ^{[1
]}

机构：

[1] UNIV BAYREUTH,W-8580 BAYREUTH,GERMANY

来源：

CHEMICAL PHYSICS | 1991年 / 149卷 / 03期

关键词：

D O I：

10.1016/0301-0104(91)90043-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The strength and symmetry of the nuclear quadrupole interaction of the following Hg-199m mercaptides were measured at room temperature by gamma-gamma-perturbed angular correlations: dithiotreitol (DTT), benzylmercaptan (BEM), 1,3-dimercaptobenzene (DMB), glycoldimercaptoacetate (GDMA), and an oligomer synthesized from 1,3-dimercaptobenzene and norbornadiene, having an average number of repeating units of seven and mercapto end groups (dimercaptotelechel: TEL 7). The data suggest an almost linear S-Hg-S bond in all cases.

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页码：437 / 443

页数：7

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